Issue 23, 1984

Rapid cleavage of chelated pyrophosphate using metal ion complexes

Abstract

Aspects of the mechanism of the rapid cleavage of P2O74– ion in Co(en2)P2O7(en [double bond, length half m-dash] ethane-1,2-diamine) by Co(tn)2(OH)(OH2)2+(tn [double bond, length half m-dash] propane-1,3-diamine) are outlined to show how the metal ions act in concert, to provide a co-ordinated nucleophile(OH) to assist the leaving group in serving a central P–O bond and in general to neutralize charge on the PO3 residues.

Article information

Article type
Paper

J. Chem. Soc., Chem. Commun., 1984, 1568-1571

Rapid cleavage of chelated pyrophosphate using metal ion complexes

I. I. Creaser, G. P. Haight, R. Peachey, W. T. Robinson and A. M. Sarageson, J. Chem. Soc., Chem. Commun., 1984, 1568 DOI: 10.1039/C39840001568

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