Intramolecular attack by co-ordinated hydroxide on one metal ion at acetonitrile bound to the other metal ion in binuclear µ-amido-octa-amminedicobalt(III) species is observed under acid conditions to give a chelated acetamide product, established by X-ray crystallographic analysis.
N. J. Curtis, K. S. Hagen and A. M. Sargeson, J. Chem. Soc., Chem. Commun., 1984, 1571 DOI: 10.1039/C39840001571
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