Highly stereoselective addition of nucleophiles to α-methyl-β-methylene carbonyl compounds combined with the hydromagnesiation reactions of 2-alkyl-substituted 1,3-dienes affords a practical, efficient stereo- and regio-controlled aldol synthesis.
F. Sato, Y. Takeda, H. Uchiyama and Y. Kobayashi, J. Chem. Soc., Chem. Commun., 1984, 1132 DOI: 10.1039/C39840001132
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