Issue 13, 1984
From the journal:

Journal of the Chemical Society, Chemical Communications

Reactivity patterns associated with pyramidal and planar phosphido-ligand geometries; synthesis and structure of [Os(PHPh)Cl(CO)2(PPh3)2] and of [Os{PH(OMe)Ph}(CO)2(PPh3)2]

D. Scott Bohle,   Tony C. Jones,   Clifton E. F. Rickard  and  Warren R. Roper  

Abstract

Deprotonation of [OsCl(PH2Ph)(CO)2(PPh3)2]+ gives the terminal phosphido-complex, [Os(PHPh)Cl(CO)2(PPh3)2], which has pyramidal geometry at P and associated nucleophilic properties, e.g., protonation and methylation at P, but [Os(PHPh)Cl(CO)2(PPh3)2] also reacts with methoxide to form the zerovalent compound [Os{PH(Ome)Ph}(CO)2(PPh3)2] suggesting the intermediacy of the planar phosphido-complex [Os(PHPh)(CO)2(PPh3)2]+.

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Article information

DOI
https://doi.org/10.1039/C39840000865
Article type
Paper

J. Chem. Soc., Chem. Commun., 1984, 865-867

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Reactivity patterns associated with pyramidal and planar phosphido-ligand geometries; synthesis and structure of [Os(PHPh)Cl(CO)2(PPh3)2] and of [Os{PH(OMe)Ph}(CO)2(PPh3)2]

D. S. Bohle, T. C. Jones, C. E. F. Rickard and W. R. Roper, J. Chem. Soc., Chem. Commun., 1984, 865 DOI: 10.1039/C39840000865

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