In the presence of a suitable nitroxide, 2-(t-butylazo)prop-2-yl hydroperoxide (1a) decomposes cleanly into hydroxyl and t-butyl radicals; the rate constant for its disappearance in cyclohexane is given by: k= 9.58 × 1014 exp. (–1.47 × 104/T)s–1.
R. D. Grant, E. Rizzardo and D. H. Solomon, J. Chem. Soc., Chem. Commun., 1984, 867 DOI: 10.1039/C39840000867
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