Issue 11, 1984
From the journal:

Journal of the Chemical Society, Chemical Communications

Synthesis of anionic sandwich compounds: [Ti(η-C6H5R)2]– and the crystal structure of [K(18-crown-6)(µ-H)Mo(η-C5H5)2]

Judith A. Bandy,   Adam Berry,   Malcolm L. H. Green,   Robin N. Perutz,   Keith Prout  and  Jean-Noel Verpeaux  

Abstract

Treatment of Mo(µ-C5H5)2H2 with potassium hydride and 18-crown-6 gives the compound [k(18-crown-6)(µ-H)Mo(η-C5H5)2] whose crystal structure has been determined; the compounds Ti(η-C6H5R)2, R = H or Me undergo reduction with potassium metal to give the salts K+[Ti(η-C6H5R)2]–, R = H or Me.

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Article information

DOI
https://doi.org/10.1039/C39840000729
Article type
Paper

J. Chem. Soc., Chem. Commun., 1984, 729-731

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Synthesis of anionic sandwich compounds: [Ti(η-C6H5R)2]– and the crystal structure of [K(18-crown-6)(µ-H)Mo(η-C5H5)2]

J. A. Bandy, A. Berry, M. L. H. Green, R. N. Perutz, K. Prout and J. Verpeaux, J. Chem. Soc., Chem. Commun., 1984, 729 DOI: 10.1039/C39840000729

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