Issue 11, 1984

Estimation of bond dissociation energies, including DH°(RSCH2–H), from barriers to internal rotation

Abstract

A Linear correlation between C–H bond dissociation energies in molecules of the type RCH2–H and the corresponding barriers to rotation about the ·CH2–R bonds is established and used to derive the Cα–H bond dissociation energy of sulphides.

Article information

Article type
Paper

J. Chem. Soc., Chem. Commun., 1984, 731-732

Estimation of bond dissociation energies, including DH°(RSCH2–H), from barriers to internal rotation

D. C. Nonhebel and J. C. Walton, J. Chem. Soc., Chem. Commun., 1984, 731 DOI: 10.1039/C39840000731

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