The crystal structure of Cu4Ac6(Ph3P)4 comprises centrosymmetrical molecules, each of which consists of a dimeric unit of Cu2Ac4, similar to that in the structure of copper(II) acetate monohydrate, with the copper(I) co-ordinated through the oxygen atom of the acetate group in both axial CuAc(Ph3P)2 units.
M. Koman, D. Valigura, E. Ďurčanská and G. Ondrejovič, J. Chem. Soc., Chem. Commun., 1984, 381 DOI: 10.1039/C39840000381
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