A new macrocyclic N-bridged species of formula [PcFe–N–FePc](Pc = phthalocyaninato anion, C32H16N82–) has been prepared by reaction of PcFe with NaN3 in α-chloronaphthalene and structurally and electronically characterized by i.r., visible, X-Ray powder, and e.s.r. measurements: one-electron oxidation leads to the cationic species [PcFe–N–FePc]+, which has been isolated as the PF6– salt.
V. L. Goedkent and C. Ercolani, J. Chem. Soc., Chem. Commun., 1984, 378 DOI: 10.1039/C39840000378
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