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Between 500 and 1000 K, well below where the carbonate-catalysed C–CO2 reactions occurs, potassium carbonate–carbon mixtures in carbon dioxide gas exchange carbon and oxygen between the CO2 and K2CO3, with two labile surface carbonate complexes as probable intermediates.
J. M. Saber, J. L. Falconer and L. F. Brown, J. Chem. Soc., Chem. Commun., 1984, 376 DOI: 10.1039/C39840000376
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