The tridentate phosphine-substituted iridium cluster,[Ir4(CO)9{(Ph2P)3CH}], has been shown by X-ray crystallography to be the first example of a phosphine-substituted tetranuclear iridium cluster in which the all-terminal co ligand configuration of the parent [Ir4(co)12]is maintained.
J. A. Clucas, M. M. Harding, B. S. Nicholls and A. K. Smith, J. Chem. Soc., Chem. Commun., 1984, 319 DOI: 10.1039/C39840000319
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