The hydrolysis (in H2O–MeCN or H2O–Me2So)and methanolysis of TsiSiR2I[Tsi =(Me3Si)3C; R = Ph or Et] give only unrearranged products TsiSiR2Y(Y = OH or OMe); thus the methanolyses of TsiSiMe2I and Tsi SiPhHI Seem likely to be SN2(intermediate)rather than SN1 processes as previously suggested.
S. A. I. Al-Shali, C. Eaborn, F. A. Fattah and S. T. Najim, J. Chem. Soc., Chem. Commun., 1984, 318 DOI: 10.1039/C39840000318
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