The direct photolysis of 1-(4-chloromethylphenyl)propene (5) in t-butyl alcohol affords products derived from both homolytic and heterolytic carbon–chlorine bond fission, whereas triplet sensitized irradiation of (5) results only in cis–trans isomerization.
S. S. Hixson and V. R. Rao, J. Chem. Soc., Chem. Commun., 1984, 65 DOI: 10.1039/C39840000065
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