trans-3,4,4a,5,6,7,8,8a-Octahydro-5,5,8a-trimethylnaphthalene-1 (2H)-one (1) was converted into the drimane sesquiterpene euryfuran (5) in 59% yield. Euryfuran was then used as a starting material for the synthesis of two other drimane natural products, confertifolin and valdiviolide. The preparation of valdiviolide constitutes the first total synthesis of this molecule.
S. V. Ley and M. Mahon, J. Chem. Soc., Perkin Trans. 1, 1983, 1379 DOI: 10.1039/P19830001379
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