Issue 24, 1983

α-Carboxylation reactions of ketones with a bromomagnesium thioureide–carbon dioxide complex

Abstract

The magnesium complex (1) has been found to undergo fixation of carbon dioxide and the resulting carboxylato-complex (2) transfers the carboxylato group to several ketones with good yields.

Article information

Article type
Paper

J. Chem. Soc., Chem. Commun., 1983, 1487-1488

α-Carboxylation reactions of ketones with a bromomagnesium thioureide–carbon dioxide complex

N. Matsumura, N. Asai and S. Yoneda, J. Chem. Soc., Chem. Commun., 1983, 1487 DOI: 10.1039/C39830001487

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