A new regioselective iodoamination reaction of allylic trichloroacetamides is described; the iodoaminoalcohols are obtained as the salts (5)via the corresponding 4,5-dihydro-1,3-oxazoles (4), and (4a) is converted by hydrolysis into the salt of the 3-amino-1,2-diol (9a).
G. Cardillo, M. Orena and S. Sandri, J. Chem. Soc., Chem. Commun., 1983, 1489 DOI: 10.1039/C39830001489
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