The hydrido-norbornadiene (nbd) complex RuHCl(nbd)(PPh3)2 exists in solution as a single isomer with a coplanar arrangement of metal, hydride, and an alkene π-bond, the requisite geometry for olefin insertion; the insertion to give an alkenyl is promoted by reaction with carbon monoxide that itself subsequently inserts to give an acyl derivative.
T. W. Dekleva and B. R. James, J. Chem. Soc., Chem. Commun., 1983, 1350 DOI: 10.1039/C39830001350
To request permission to reproduce material from this article, please go to the Copyright Clearance Center request page.
If you are an author contributing to an RSC publication, you do not need to request permission provided correct acknowledgement is given.
If you are the author of this article, you do not need to request permission to reproduce figures and diagrams provided correct acknowledgement is given. If you want to reproduce the whole article in a third-party publication (excluding your thesis/dissertation for which permission is not required) please go to the Copyright Clearance Center request page.
Read more about how to correctly acknowledge RSC content.
Please wait while we load your content...