Issue 21, 1983
From the journal:

Journal of the Chemical Society, Chemical Communications

Stereochemical control and mechanistic aspects of the alkylation of [(η5-C5H5)Fe(L)(CO)(COCHR)]–Li+(L = PPh3, PPh2NEt2; R = Me, Et): X-ray crystal structure of [(η5-C6H5)Fe(PPh3)(CO){COCH(Me)Et}]

Gordon J. Baird,   Judith A. Bandy,   Stephen G. Davies  and  Keith Prout  

Abstract

Determination of the molecular structure of [(η5-C5H5)Fe(PPh3)(CO){COCH(Me)Et}], formed in the diastereoselective methylation of [(η5-C5H5)Fe(PPh3)(CO)(COCHEt)]–Li+, allows the assignment of the relative configuration of the new chiral centre and indicates the origin of the high diastereoselectivities observed in this type of reaction.

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Article information

DOI
https://doi.org/10.1039/C39830001202
Article type
Paper

J. Chem. Soc., Chem. Commun., 1983, 1202-1203

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Stereochemical control and mechanistic aspects of the alkylation of [(η5-C5H5)Fe(L)(CO)(COCHR)]–Li+(L = PPh3, PPh2NEt2; R = Me, Et): X-ray crystal structure of [(η5-C6H5)Fe(PPh3)(CO){COCH(Me)Et}]

G. J. Baird, J. A. Bandy, S. G. Davies and K. Prout, J. Chem. Soc., Chem. Commun., 1983, 1202 DOI: 10.1039/C39830001202

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