Monomeric methyleneamines (1), formed from N-(alkoxymethyl)arylamines (3), are stable at –60 °C and may be trapped with organometallic reagents to provide the N-alkylarylamines (7).
J. Barluenga, A. M. Bayón and G. Asensio, J. Chem. Soc., Chem. Commun., 1983, 1109 DOI: 10.1039/C39830001109
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