Issue 19, 1983

Polar effect in the reaction of photoenol-type diradical with molecular oxygen

Abstract

Measurement of product [(4) and (5)] quantum yields indicated that reactions of molecular oxygen with diradicals photogenerated from 2,4,6-tri-isopropylbenzophenones (3ae) were accelerated by the presence of both electron-donating (OMe and Me) and electron-withdrawing (Cl and CF3) substituents, this acceleration probably resulted from the zwitterionic nature of the diradicals.

Article information

Article type
Paper

J. Chem. Soc., Chem. Commun., 1983, 1110-1111

Polar effect in the reaction of photoenol-type diradical with molecular oxygen

Y. Ito, H. Nishimura, H. Shimizu and T. Matsuura, J. Chem. Soc., Chem. Commun., 1983, 1110 DOI: 10.1039/C39830001110

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