The e.s.r. spectrum of bicyclo[1.1.1]pent-1-yl radicals shows a very large hyperfine splitting from the bridgehead γ-hydrogen; this is probably due to the through space and through bond orbital interactions reinforcing one another.
B. Maillard and J. C. Walton, J. Chem. Soc., Chem. Commun., 1983, 900 DOI: 10.1039/C39830000900
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