Issue 12, 1982
From the journal:

Journal of the Chemical Society, Faraday Transactions 2: Molecular and Chemical Physics

Vibrational and electronic spectra of the UO2(NO3)42– ion

Colin D. Flint  and  Prasanta Sharma  

Abstract

The luminescence and absorption spectra of single crystals of K2UO2(NO3)4, Rb2UO2(NO3)4 and (NH4)2UO2(NO3)4·2H2O have been measured at liquid-helium temperatures. These spectra indicate a highly symmetric environment for the uranyl ion. Infrared, Raman and electronic spectra show the presence of two types of coordinated nitrate groups. The anion therefore probably has a trans-UO2(ONO2)2(O2NO) structure with both monodentate and bidentate nitrato ligands.

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Article information

DOI
https://doi.org/10.1039/F29827802155
Article type
Paper

J. Chem. Soc., Faraday Trans. 2, 1982,78, 2155-2160

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Vibrational and electronic spectra of the UO2(NO3)42– ion

C. D. Flint and P. Sharma, J. Chem. Soc., Faraday Trans. 2, 1982, 78, 2155 DOI: 10.1039/F29827802155

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