The structures of the hydrated zinc(II) and nitrate ions in 4.72 mol dm–3 aqueous Zn(NO3)2 have been determined by X-ray diffraction. Octahedral coordination in Zn2+aq is confirmed and the average Zn—Owater distance is 2.17 (4)Å; there is no evidence for coordination by NO–3. Approximately three water molecules are hydrogen bonded to each nitrate O-atom.
S. P. Dagnall, D. N. Hague and A. D. C. Towl, J. Chem. Soc., Faraday Trans. 2, 1982, 78, 2161 DOI: 10.1039/F29827802161
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