Issue 24, 1982
From the journal:

Journal of the Chemical Society, Chemical Communications

Improved synthesis and electronic structure of the 19-and 20-electron complexes [Fe(η6-C6Me6)2]n+, n= 1,0

Pascal Michaud,   Jean-Pierre Mariot,   François Varret  and  Dider Astruc  

Abstract

The 19- and 20-electron complexes [Fe(η6-C6Me6)2]n(n= 1,0) are best synthesized by Na/Hg reduction of [Fe(η6-C6Me6)2]2[PF6–]2; the extremely negative value of the quadrupole splitting for [Fe(η6-C6Me6)2], comparison of Mössbauer parameters of [Fe(η6-C6Me6)2]n+(n= 0,1,2), and the temperature dependence of the quadrupole splitting for [Fe(η6-C6Me6)2]+ indicate high metal character for the antibonding e1* orbital and rhombic distortion of the Jahn–Teller-active FeI complex.

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Article information

DOI
https://doi.org/10.1039/C39820001383
Article type
Paper

J. Chem. Soc., Chem. Commun., 1982, 1383-1385

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Improved synthesis and electronic structure of the 19-and 20-electron complexes [Fe(η6-C6Me6)2]n+, n= 1,0

P. Michaud, J. Mariot, F. Varret and D. Astruc, J. Chem. Soc., Chem. Commun., 1982, 1383 DOI: 10.1039/C39820001383

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