Various functionalized disubstituted acetylenes, including esters, are prepared metathetically with high selectivity on molybdenum based homogeneous catalytic systems; this procedure is a useful tool for the synthesis of acetylenes, wnich can provide cis- or trans-olefins by further selective hydiogenation.
M. Petit, A. Mortreux and F. Petit, J. Chem. Soc., Chem. Commun., 1982, 1385 DOI: 10.1039/C39820001385
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