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Partial photolysis with plane-polarized light of phenyl azide in N2 matrices at 12 K yields samples with dichroic i.r. spectra, analysis of which excludes C2v and bisected-Cs geometries for phenyl azide, and suggests a planar-Cs or nearly planar conformation.
I. R. Dunkin, J. Chem. Soc., Chem. Commun., 1982, 1348 DOI: 10.1039/C39820001348
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