3-Oxopyrans, bearing unsaturated side Chains, can undergo intramolecular reactions, either by thermal or base-catalysed processes, to yield bicyclic adducts and affording, for example, a simple entry into the perhydroazulene system.
P. G. Sammes and L. J. Street, J. Chem. Soc., Chem. Commun., 1982, 1056 DOI: 10.1039/C39820001056
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