The oxidation of [Fe2(CO)6(η4,η′4-C16H18)] and of [Fe2(CO)6(η4,η′4-C16H18)] ieads to stereospecific cyclopropane ring-opening and the isolation of (4) and (5) with exocyclic trans-and cis-double bonds, respectively; (5) is reduced to (6) with cyclobutane ring formation.
N. G. Connelly, A. R. Lucy, R. M. Mills, J. B. Sheridan, M. W. Whiteley and P. Woodward, J. Chem. Soc., Chem. Commun., 1982, 1057 DOI: 10.1039/C39820001057
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