Issue 15, 1982

The beta-hop: [2-2H3,2-13C1]acetate as a probe for 1,2-hydride shifts in the biosynthesis of natural products

Abstract

The postulated migration of hydrogen from c-5 to c-4 in the biosynthesis of the potato phytoalexin reshitin (1) has been confirmed by incorporation of [2-2H3,2-13C1]acetate and direct observation of the predicted β-shift of the C-5 resonance due to 2H at C-4.

Article information

Article type
Paper

J. Chem. Soc., Chem. Commun., 1982, 880-881

The beta-hop: [2-2H3,2-13C1]acetate as a probe for 1,2-hydride shifts in the biosynthesis of natural products

A. Stoessl and J. B. Stothers, J. Chem. Soc., Chem. Commun., 1982, 880 DOI: 10.1039/C39820000880

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