Systematic syntheses of heterobimetallic complexes of platinum with rhodium(I), iridium(I), iridium(III) or tungsten(0) bridged by Ph2PCH2PPh2
Abstract
Complexes of type trans-[Pt(CCR)2(η1-Ph2PCH2PPh2)2](R = Me, Ph, or p-tolyl), are used to effect systematic, high-yield syntheses of heterobimetallic complexes with RhI, IrI, IrIII(bridging hydride), and Wo.