We have resolved photoelectron peaks from the ionization of all three metal–metal molecular orbitals [b2g(δ), eu(π), and a1g(σ)] that form the metal–metal quadruple bond in W2(O2CCF3)4.
G. M. Bancroft, E. Pellach, A. P. Sattelberger and K. W. McLaughlin, J. Chem. Soc., Chem. Commun., 1982, 752 DOI: 10.1039/C39820000752
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