Heme model compounds have been synthesized incorporating a high spin iron(III) ion and a copper(II) ion to form a Fe–O–Cu complex showing antiferromagnetic coupling with –3J= 132 ± 5 cm–1.
C. K. Chang, M. S. Koo and B. Ward, J. Chem. Soc., Chem. Commun., 1982, 716 DOI: 10.1039/C39820000716
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