Issue 4, 1981

Spectrochemistry of solutions. Part 12. Cyano-complexes of silver(I) in solution in liquid ammonia

Abstract

Raman spectra of cyano-complexes of silver(I) in liquid ammonia solution have been interpreted to show the existence, in equilibrium, of the following species: AgCN, AgNC, [Ag(CN)2], [Ag(CN)(NC)], [Ag(NC)2], [Ag(CN)3]2–, [Ag2(CN)]+, [Ag2(CN)2], [Ag2(CN)3], [MAg2(CN)5]2–(M = Na+ or K+), and [MAg(CN)3](M = Li+, Na+, or K+). The factors affecting the linkage isomerism, ion aggregation, ion pairing, and silver complexation are discussed.

Article information

Article type
Paper

J. Chem. Soc., Dalton Trans., 1981, 968-975

Spectrochemistry of solutions. Part 12. Cyano-complexes of silver(I) in solution in liquid ammonia

P. Gans, J. B. Gill, M. Griffin and P. C. Cahill, J. Chem. Soc., Dalton Trans., 1981, 968 DOI: 10.1039/DT9810000968

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