Lithium enolates from pentan-3-one, cyclo-hexanone, acetophenone, and mesityl oxide react with some representative (acyclic and cyclic) allylic acetates in a palladium-catalysed alkylation in good yields and under mild conditions; the substitution is shown to proceed with retention of configurations.
J. Fiaud and J. Malleron, J. Chem. Soc., Chem. Commun., 1981, 1159 DOI: 10.1039/C39810001159
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