Issue 15, 1981

Solvolysis mechanisms for benzyl substrates

Abstract

The solvolysis of p-methoxybezyl bromide in 80%V/V dioxan–water involves trappable carbonium ion intermediates as shown by increases in rate and α-D isotope effect with increasing perchlorate ion concentation and reducations in rate and α-D isotope effect with increasing concentration of common ion salt.

Article information

Article type
Paper

J. Chem. Soc., Chem. Commun., 1981, 737-738

Solvolysis mechanisms for benzyl substrates

V. P. Vitullo, J. Grabowski and S. Sridharan, J. Chem. Soc., Chem. Commun., 1981, 737 DOI: 10.1039/C39810000737

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