Issue 14, 1981
From the journal:

Journal of the Chemical Society, Chemical Communications

Proton-induced ligand uptake by [Mn2(CO)5(Ph2PCH2PPh2)2] to give hydrogen-bridged dimanganese complexes

Helen C. Aspinall  and  Antony J. Deeming  

Abstract

[Mn2(CO)5(dpm)2](dpm = Ph2PCH2PPh2) does not react with nucleophiles but reacts readily with acids absorbing CO to give [Mn2(µ-H)(CO)6(dpm)2]+ which with LiBHEt3 regenerates [Mn2(CO)5(dpm)2]; if other anionic or neutral ligands are present, these may be co-ordinated on protonation instead of CO.

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Article information

DOI
https://doi.org/10.1039/C39810000724
Article type
Paper

J. Chem. Soc., Chem. Commun., 1981, 724-724

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Proton-induced ligand uptake by [Mn2(CO)5(Ph2PCH2PPh2)2] to give hydrogen-bridged dimanganese complexes

H. C. Aspinall and A. J. Deeming, J. Chem. Soc., Chem. Commun., 1981, 724 DOI: 10.1039/C39810000724

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