SCHEDULED MAINTENANCE
Gas-phase thermolysis of the dimethylamino-azoalkene (1) gives the formamidine (2) by loss of HCN: in contrast, the related 1,5-diazapentadiene (4) under more forcing conditions gives aniline (30%) and N-methyl-pyrrole (43%).
H. McNab and E. Murray, J. Chem. Soc., Chem. Commun., 1981, 722 DOI: 10.1039/C39810000722
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