The flash vacuum pyrolysis of N-benzyl-2-phenyl-1,3,4-oxadiazolin-5-one generates a nitrile N-imide which rearranges to a diazoalkane via a 1,3-sigmatropic benzyl shift.
A. Padwa, T. Caruso and D. Plache, J. Chem. Soc., Chem. Commun., 1980, 1229 DOI: 10.1039/C39800001229
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