Issue 24, 1980
From the journal:

Journal of the Chemical Society, Chemical Communications

Novel reactivity and low temperature (–60 °C)X-ray crystal structure determination of Ru(CO)2(η2-SO2·SO2)(PPh3)2

David C. Moody  and  Robert R. Ryan  

Abstract

Crystals of the title complex have been obtained from SO2 saturated benzene–heptane solutions of Ru(CO)3(PPh3)2, and an X-ray crystal structure determination at –60 °C has shown not only η2-SO2 co-ordination to the ruthenium, but also a second molecule of SO2 co-ordinated to the terminal oxygen of the η2-SO2; reaction with excess of SO2 and PPh3 under anaerobic conditions results in stoicheiometric production of Ru(SO4)(CO)2(PPh3)2 plus PPh3S.

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Article information

DOI
https://doi.org/10.1039/C39800001230
Article type
Paper

J. Chem. Soc., Chem. Commun., 1980, 1230-1231

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Novel reactivity and low temperature (–60 °C)X-ray crystal structure determination of Ru(CO)2(η2-SO2·SO2)(PPh3)2

D. C. Moody and R. R. Ryan, J. Chem. Soc., Chem. Commun., 1980, 1230 DOI: 10.1039/C39800001230

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