Products formed from the decomposition of the 4a-peroxy-anion of the flavin (1d) are only accountable through reactions involving the 4a-hydroperoxide anion; kinetic and product studies both argue against the involvement of a 4a → 10a peroxy-anion migration.
T. C. Bruice and A. Miller, J. Chem. Soc., Chem. Commun., 1980, 693 DOI: 10.1039/C39800000693
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