Reactions of toluene-p-sulphonic thioanhydride with sulphur nucleophiles
Abstract
Ethoxythiocarbonyl p-tolylsulphonyl disulphide (5), benzylthio(thiocarbonyl)p-tolylsulphonyl disulphide (1c), and NN-dimethylthiocarbamoyl p-tolylsulphonyl disulphide (10) are formed in the reactions of toluene-p-sulphonic thioanhydride (3) with O-ethyl dithiocarbonate (4), benzyl trithiocarbonate (2), and NN-dimethyl dithiocarbamate (9) ions, respectively.