The 1H-n.m.r. spectra of dimethylacetamide in the gas phase give an activation energy of ΔF298≠= 15·64 ± 0·1 kcal mol–1 for the rotation about the amide C–N bond, significantly smaller than that found in solution.
M. Feigel, J. Chem. Soc., Chem. Commun., 1980, 456 DOI: 10.1039/C39800000456
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