The photo-oxygenation of diphenylacetylene (1) is efficiently sensitized (via electron transfer) with dicyanoanthracene (Φ=ca. 0·15), but is sensitized very poorly (Φ < 0·001) with tetracyanoanthracene (TCA); catalysis by acids and nucleophiles substantially increases the quantum yield of photo-oxygenation through reactions competing with the reverse electron transfer between (TCA)–˙ and (1)+˙.
S. L. Mattes and S. Farid, J. Chem. Soc., Chem. Commun., 1980, 457 DOI: 10.1039/C39800000457
To request permission to reproduce material from this article, please go to the Copyright Clearance Center request page.
If you are an author contributing to an RSC publication, you do not need to request permission provided correct acknowledgement is given.
If you are the author of this article, you do not need to request permission to reproduce figures and diagrams provided correct acknowledgement is given. If you want to reproduce the whole article in a third-party publication (excluding your thesis/dissertation for which permission is not required) please go to the Copyright Clearance Center request page.
Read more about how to correctly acknowledge RSC content.
Please wait while we load your content...