Issue 3, 1980
From the journal:

Journal of the Chemical Society, Chemical Communications

Synthesis and characterization of thiovanadyl (V[double bond, length half m-dash]S2+) complexes

Kenneth P. Callahan,   Paul J. Durand  and  Philip H. Rieger  

Abstract

The existence of the thiovanadyl ion, V[double bond, length half m-dash]S2+, has been established by reaction of V[double bond, length half m-dash]O(salen) and V[double bond, length half m-dash]O(acen)[H2salen =NN′-ethylenebis(salicylideneamine); H2acen =NN′-ethylenebis(acetylacetonylideneamine)] with B2S3 to form the thiovanadyl compounds; infrared and e.s.r. spectroscopy indicate that the V[double bond, length half m-dash]S bond has greater covalency but is weaker than its vanadyl analogues.

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Article information

DOI
https://doi.org/10.1039/C39800000075
Article type
Paper

J. Chem. Soc., Chem. Commun., 1980, 75-76

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Synthesis and characterization of thiovanadyl (V[double bond, length half m-dash]S2+) complexes

K. P. Callahan, P. J. Durand and P. H. Rieger, J. Chem. Soc., Chem. Commun., 1980, 75 DOI: 10.1039/C39800000075

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