Issue 3, 1980
From the journal:

Journal of the Chemical Society, Chemical Communications

Electroreduction of linear trimetallic complexes: M–Hg–M, (M–Au–M)–, M–PtL2–M [M = Co(CO)4, Fe(CO)3NO, Mn(CO)5, Cr(CO)3(η-C5H5), Mo(CO)3(η-C5H5), or W(CO)3(η-C5H5); L = ButNC or C6H11NC]; unexpected generation of radicals

Paul Lemoine,   Alain Giraudeau,   Maurice Gross  and  Pierre Braunstein  

Abstract

Cathodic reduction of PtII isocyanide compounds M–PtIIL2–M on platinum and gold electrodes in an aprotic medium leads to unexpected paramagnetic PtI species, whereas under the same conditions M–Hg–M and (M–Au–M)– exhibit predictable metal–metal bond cleavage.

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Article information

DOI
https://doi.org/10.1039/C39800000077
Article type
Paper

J. Chem. Soc., Chem. Commun., 1980, 77-78

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Electroreduction of linear trimetallic complexes: M–Hg–M, (M–Au–M)–, M–PtL2–M [M = Co(CO)4, Fe(CO)3NO, Mn(CO)5, Cr(CO)3(η-C5H5), Mo(CO)3(η-C5H5), or W(CO)3(η-C5H5); L = ButNC or C6H11NC]; unexpected generation of radicals

P. Lemoine, A. Giraudeau, M. Gross and P. Braunstein, J. Chem. Soc., Chem. Commun., 1980, 77 DOI: 10.1039/C39800000077

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