N-(1,2-Dihydro-2-oxoquinolin-1-yl)-N-(1-methylallyl)-4-chlorobenzenesulphenamide (5) has previously been isolated in two stereoisomeric forms. From examination of a number of analogues of (5), it is concluded that the phenomenon which allows isolation of these stereoisomers is restricted rotation around the N–N bond.
R. S. Atkinson, B. D. Judkins and B. Patwardhan, J. Chem. Soc., Perkin Trans. 2, 1979, 1490 DOI: 10.1039/P29790001490
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