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Issue 20, 1979
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The structures of the carbenoid CH2FLi: ab initio MO calculations

Abstract

The model carbenoid, CH2FLi, is indicated by ab initio molecular orbital calculations to have a peculiar umbrella shaped (‘inverted carbon’) structure and CH2Li+ F ion pair character; metallocarbenium ions may thus be the reactive species in carbenoid reactions.

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Article information


J. Chem. Soc., Chem. Commun., 1979, 883-884
Article type
Paper

The structures of the carbenoid CH2FLi: ab initio MO calculations

T. Clark and P. V. R. Schleyer, J. Chem. Soc., Chem. Commun., 1979, 883
DOI: 10.1039/C39790000883

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