Through their first excited singlet states, cyanothiophens undergo phototranspositions for which permutation pattern analysis and the isolation of furan–thiabicyclopentene adducts from irradiations in furan suggest a mechanism involving 2,5-bonding followed by a ‘walk’ of the sulphur atom.
J. A. Barltrop, A. C. Day and E. Irving, J. Chem. Soc., Chem. Commun., 1979, 881 DOI: 10.1039/C39790000881
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