Issue 17, 1979
From the journal:

Journal of the Chemical Society, Chemical Communications

Reaction of α-phosphino functional carbanions with co-ordinated nitriles. Synthesis of bis-chelate (P,N) platinum complexes; X-ray crystal and molecular structure of trans-Pt[P(Ph)2C(CO2Et)C(Ph)NH]2

Pierre Braunstein,   Dominique Matt,   Yves Dusausoy  and  J. Protas  

Abstract

The α-phosphino carbanions Ph2P[C with combining macron]HY (Y = CO2Et or CN) react with the co-ordinated nitrile ligand of cis-Pt(PhCN)2Cl2 to give new bis-chelate (P, N) platinum complexes P[graphic omitted]H]2; the structure of one of them (Y = CO2Et) has been determined by X-ray diffraction.

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Article information

DOI
https://doi.org/10.1039/C39790000763
Article type
Paper

J. Chem. Soc., Chem. Commun., 1979, 763-764

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Reaction of α-phosphino functional carbanions with co-ordinated nitriles. Synthesis of bis-chelate (P,N) platinum complexes; X-ray crystal and molecular structure of trans-Pt[P(Ph)2C(CO2Et)C(Ph)NH]2

P. Braunstein, D. Matt, Y. Dusausoy and J. Protas, J. Chem. Soc., Chem. Commun., 1979, 763 DOI: 10.1039/C39790000763

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