Issue 17, 1979

Reductive isomerisation in superacidic media: evidence for a 1,3 hydride shift in a steroid

Abstract

The major component of the reaction of 7β-methyl-14-iso-oestr-4-ene-3,17-dione in HF–SbF5–methyl-cyclopentane at 0 °C has shown to result from 1,3 hydride shift followed by kinetically controlled intermolecular hydride transfer.

Article information

Article type
Paper

J. Chem. Soc., Chem. Commun., 1979, 765-766

Reductive isomerisation in superacidic media: evidence for a 1,3 hydride shift in a steroid

R. Jacquesy and C. Narbonne, J. Chem. Soc., Chem. Commun., 1979, 765 DOI: 10.1039/C39790000765

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